Hi, I understand you want the report structure designed, and a way to fetch data from MySQL, populate the HTML (this will happen with PHP), and output as a PDF. I can do this for you, I can:
1. Design the report provided (HTML and CSS)
2. Write a PHP script to allow fetching data from the database, placing them in the report, exporting to PDF, and saving on the file system.
I'm a web developer and designer with years of experience and I've worked on countless custom PHP scripts to add functionality similar to this.
Feel free to contact me.